Effect of core-shell micelle formation on the redox properties of phenothiazine-labeled poly(ethyl glycidy ether)-block-poly(ethylene oxide)

Redox properties of phenothiazine-labeled poly(ethyl glycidy ether)-block-poly(ethylene oxide) (PT-EGE_n-b-EO_m) are reversibly changed by core-shell micelle formation. In the temperature range higher than the critical micellization temperature (cmt), the anodic potential of PT group positively shifts and concomitantly its anodic current decrease, or levels off compared to those of the reference polymer PT-EO_m without the thermo-responsive EGE_n segment. The former alteration is caused by incorporation of hydrophobic PT groups into a core of the micelle and the latter by the decrease in the diffusion coefficient of PT groups due to formation of the core-shell micelles. The cmt value and the temperature-dependent alteration in the redox properties strongly depend on the polymer structure, especially the length of thermo-responsive EGE_n segment. The electrochemically determined hydrodynamic radii of the polymer aggregates seem to be overestimated, compared to the values reported for the aggregates of other thermo-responsive polymers with similar molecular weights, implying the presence of electrochemically inactive PT groups in the copolymers having longer thermo-responsive segments.     

Die quantitative Verfolgung des Sulfurierungsprozesses

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On the Hausdorff dimension of generalized Besicovitch-Eggleston sets of d-tuples of numbers

We give a systematic and detailed account of the Hausdorff dimensions of sets of d-tuples of numbers defined in terms of the asymptotic behaviour of the frequencies of strings of digits in their N-adic expansion.     

Measurement of circular dichroism spectra of liquid/liquid interface by centrifugal liquid membrane method.

The direct measurement of the circular dichroism (CD) spectra of liquid/liquid interface has been achieved for the first time by the centrifugal liquid membrane (CLM) method combined with a conventional CD spectropolarimetry. In the sample chamber of the CD spectropolarimeter, a cylindrical glass cell containing small amounts of organic and aqueous phases was rotated at ca. 7000 rpm to generate a two-phase liquid membrane with a high specific interfacial area. The CD spectra of the J-aggregate of protonated 5,10,15,20-tetraphenylporphyrin formed at the toluene/sulfuric acid interface in the rotating cell have been measured. The results demonstrated the novelty and advantages of this method.     

The global Markov property for lattice systems

We prove the global Markov property for lattice systems of classical statistical mechanics, with bounded spins and finite range interactions. The method uses the one developed by two of us to prove the global Markov property of Euclidean generalized random fields. The result shows that the systems considered have a transition matrix, which together with a distribution on a hyperplane, describes completely the system.     

Technology showcase electronic penetrometer for field tests

The design and construction of a cone penetrometer for field use is described. The penetrometer is mounted on a frame to which two wheels are fitted for towing the device from one test site to the next. An electric motor drives the penetrometer during the test and simultaneous readings are performed of both cone depth and penetration resistance. The device weighs 70 kg and the maximum force on the cone typically exceeds 1.2 kN. The acquired data are transferred to a microcomputer and after each penetration the result is presented to the operator in graphic form. The microcomputer is equipped with a fairly large RAM memory which serves as storage medium for data during measuring work. Afterwards, data are easily moved to a mainframe computer for analysis.     

On the superconductivity in β-beryllium and related phases

Two high temperature beryllium allotropes have been stabilized at room temperature through the addition of transition elements. Superconductivity has been observed in almost all of them. Beryllium films reported superconducting in the past appear in all probability to require the presence of transition element impurities, in order to show the phenomenon.     

Ein supraleitender Gleichrichter und Verstärker

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